A theoretical and experimental study of phosphate ester inhibitors for AISI 1018 in carbon dioxide-saturated 3.5 wt% NaCl solution

Phosphate ester was investigated as a corrosion inhibitor for AISI 1018 carbon steel in carbon dioxide-saturated chloride solutions at different temperatures and pressures. The corrosion tests were realized by electrochemical techniques, weight loss measurements, bubble tests, and a high-pressure/high-temperature autoclave system. The corrosion tests demonstrated that the investigated molecule is an excellent corrosion inhibitor. The inhibiting effect is even bigger at high pressure and temperature than at atmospheric pressure and room temperature. The thermodynamic parameters were calculated and determined to obey the Langmuir isotherm. Polarization studies revealed that the evaluated inhibitor is a mixed type.     

Fast filling strategy of type III on-board hydrogen tank based on time-delayed method

In order to study the fast filling problem of the type III on-board hydrogen tank, a 3D computational fluid dynamics (CFD) simulation model is proposed. Several simulation calculations are completed to simulate the fast filling process under different initial conditions. In order to control the temperature rise during the fast filling process, the effects of different mass flow rates are studied. Based on the control of mass flow rate, various time-delayed filling strategies for different conditions are proposed to meet the requirement of shortening the filling time as much as possible without exceeding the maximum temperature limit. It is found that if the delay duration is determined, how the filling time is allocated has little effect on the final temperature rise. The proposed strategy can complete the filling within 155s in a general environment, which saves 62% of the time compared with the filling with constant mass flow rate. This research provides the theoretical basis and technical support for mass flow control strategies of fast filling in the hydrogen refueling stations and has guiding significance for the actual filling process of large-capacity hydrogen tanks.     

Effects of hydrocarbon impurities,vibrational relaxation,and boundary-layer-induced pressure rise on the ignition of H2–O2‒Ar mixtures behind reflected shock waves

The results of an experimental and theoretical study of the ignition of H₂–O₂?Ar mixtures behind reflected shock waves are reported. The experiments are performed with mixtures containing from 0.15 to 8.0% H₂ and from 0.75 to 2.0% O₂ at temperatures of 980–1800 K and a total gas concentration of (1.0 ± 0.1) × 10^?5 mol/cm³. The progress of the process is monitored by recording the time evolution of the pressure behind the reflected shock wave and the intensity of the chemiluminescence of electronically excited OH1 radicals (λ = 308 ± 2.5 nm). A numerical model capable of predicting the effects of additional factors, such as hydrocarbon impurities, the vibrational relaxation of the test mixture, and boundary-layer-induced pressure rise, is developed and used to simulate our own and published experimental data on the ignition of H₂–O₂?Ar mixtures. It is demonstrated that the best agreement between experimental and theoretical results is achieved when all the additional factors are taken into account. A sensitivity analysis shows that the effects of the vibrational relaxation of the test mixture and the presence of hydrocarbon impurities are significant only for lean mixtures, whereas the influence of the boundary-layer-induced pressure rise is important across a wide range of stoichiometries at long ignition delay times. Additionally, an analytical model is developed, which takes into account the finite time of the chain?propagation reactions O + H₂ and OH + H₂. The predictions of the numerical and analytical models are demonstrated to be in close agreement for a wide range of mixture compositions and experimental conditions.     

基于多因素耦合分析的冲击地压卸压技术研究

为有效预防ZF2803工作面的冲击地压,本文采用多因素耦合分析法研究了初次来压、见方、煤柱、断层、邻近空区支承压力、煤层厚度变化及巷道底煤等7个因素的单独影响区域及叠加效果,确定了7个危险区:中等冲击危险区4个、强冲击危险区3个,给出了相应的煤层及底板大钻孔预卸压措施,工业性应用取得了良好的防治效果。     

矿井风门漏风监测系统的研究及应用

为了有效监控煤矿井下风门是否漏风、保证煤矿风量的充足,采用压差法测风技术和软件控制技术,开发了风门漏风监测系统。系统通过在线监测风门两侧的压差实时动态掌握在用风门良好状态,对漏风风门及时报警。     

Simulation and analysis of dual-reflux pressure swing adsorption using silica gel for blue coal gas initial separation

A dual-reflux pressure swing adsorption (DR-PSA) process was proposed and simulated to initially separate the blue coal gas, aiming to capture carbon dioxide (CO₂) and enrich hydrogen (H₂), simultaneously. With a feed flow rate of 7.290 slpm, a light product reflux flow rate of 0.505 slpm and the heavy product reflux flow rate of 3.68 slpm, the developed DR-PSA process could capture CO₂ up to 64.01% with a recovery of 99.60% and enrich H₂ up to 34.66% with a recovery of 97.63% from the blue coal gas (36.2% N₂/28.5% H₂/13.9% CO/12.7% CO₂/8.7% CH₄). In addition, in order to optimize the process, the effects of various operating parameters on the DR-PSA process performance in terms of product purity and recovery were discussed in detail, including the feed position, the light product reflux ratio and the heavy product reflux ratio. Moreover, the dynamic distribution behaviors of pressure, temperature and gas-solid concentration were presented to explain and evaluate the process separation performance in depth under different operating conditions.     

Design and computational analysis of a metal hydride hydrogen storage system with hexagonal honeycomb based heat transfer enhancements-part A

In this study, design and performance analysis is carried out for a 10 kWh metal hydride based hydrogen storage system. The system is equipped with distinctive aluminium hexagonal honeycomb based heat transfer enhancements (HTE) having higher surface area to volume ratio for effective heat transfer combined with low system weight addition. The system performance was studied under different operating conditions. The optimum absorption condition was achieved at 35 bar with water at room temperature as heat transfer fluid where up to 90% absorption was completed in 7200 s. The performance of the reactor was observed to significantly improve upon the addition of the HTE network at a minimal system weight penalty.     

Synthetic copolymer (AM/AMPS/DMDAAC/SSS) as rheology modifier and fluid loss additive at HTHP for water-based drilling fluids

In the petroleum industry, high temperature and high pressure (HTHP) would dramatically worsen rheological properties and increase fluid loss volumes of drilling fluids. Synthetic polymer as an indispensable additive has attracted more and more attention recently. In this article, a new copolymer (named AADS) of 2-acrylamide-2-methylpropanesulfonic acid, acrylamide, dimethyl diallyl ammonium chloride, and sodium styrene sulfonate was synthesized through aqueous solution polymerization. The chemical structure of the copolymer was characterized by Fourier transform infrared spectroscopy and nuclear magnetic resonance. Moreover, its thermal stability was simultaneously analyzed using a differential scanning calorimetry. The results showed that the synthetic polymer contained all the designed functional groups, and its structure was consistent to the desired one. Under contamination of sodium chloride, AADS solution maintained relatively high viscosity in high concentration brine, showing a good antisalt capacity. Furthermore, the effect of AADS content and temperature on rheological behavior and fluid loss volume of the water-based drilling fluid (WBDF) containing the synthesized product were investigated according to the American Petroleum Institute standard. Results showed that the rheological and filtration properties of the prepared WBDF were improved with the increase in the AADS concentration before and after the thermal aging test. In addition, in the temperature range of 80–240 °C, a reversible rheological behavior was observed during the heating–cooling process, and the HTHP fluid loss was controlled within 22.5 mL, suggesting that the copolymer AADS was suitable for making WBDF s with high temperature resistance. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47813.     

Impact of military type footwear and load carrying workload on postural stability

Postural stability has been shown to be impacted by footwear and task performed. This study analysed the impact of two military footwear, standard boot (STB) and minimalist boot (MTB) on postural stability, before (PRE) and after (POST) a load carriage task. Sixteen participants were tested for postural stability using sensory organisation and motor control tests on Neurocom Equitest?. Postural sway, equilibrium scores and postural latencies were analysed using a two-factor repeated measures ANOVA: boot type (STB-MTB)?×?time (PRE-POST) load carriage task. Significantly greater postural sway variables, lower balance scores and slower postural latencies were seen in STB and POST load carriage conditions (p?<?.05). The results suggest that MTB exhibited greater balance compared to STB in balance conditions that rely on somatosensory feedback and that balance is lowered after a load carriage task. Decrements in postural stability could be attributed to boot design characteristics and muscular exertion due to the load carriage task.

Practitioner Summary: Maintaining optimal postural stability is crucial in military. Impact of military footwear types and load carriage task on postural stability are addressed. Findings provide footwear design and physical exertion implications on postural stability leading to potential interventions that reduce postural stability decrements; thereby, reducing potential falls and fall related injuries.